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( Nonpolar) In chemistry, polarity refers to the dipole-dipole intermolecular forces between the slightly positively-charged end of one molecule to the negative end of another or the same molecule. Molecular polarity is dependent on the difference in electronegativity between atoms in a compound and the asymmetry of the compound's structure. For example, water is thought to be polar because of the unequal sharing of its electrons. However, methane is considered non-polar because the carbon shares the hydrogen atoms uniformly. Polarity underlies surface tension.

Electrons are not always shared equally between two bonding atoms one atom might exert more of a force on the electron cloud than the other. This "pull" is termed electronegativity and measures the attraction for electrons a particular atom has. The unequal sharing of electrons within a bond leads to the formation of an electric dipole a separation of positive and negative electric charge.

Atoms with high electronegativities - such as fluorine, oxygen, and nitrogen - exert a greater pull on electrons than atoms with lower electronegativities. In a bonding situation this can lead to unequal sharing of electrons between atoms as electrons will spend more time closer to the atom with the higher electronegativity.

Bonds can fall between one of two extremes - being completely non-polar or completely polar. A completely non-polar bond occurs when the electronegativities are identical and therefore possess a difference of zero. A completely polar bond is more correctly termed ionic bonding and occurs when the difference between electronegativities is large enough that one atom takes an electron from the other. The terms "polar" and "non-polar" bonds usually refer to covalent bonds. To determine the polarity of a covalent bond using numerical means, the difference between the electronegativity of the atoms is taken. If the result is between 0.4 and 1.7 then, generally, the bond is polar covalent.

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